 
data_shelxl 
 
_audit_creation_method            'CrystalClear-SM Expert 2.1 b25 (Rigaku, 2013)'
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'C25 H32 Cl3 N3 O7' 
_chemical_formula_weight          592.89 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0181   0.0091 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0311   0.0180 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0492   0.0322 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cl'  'Cl'   0.3639   0.7018 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            triclinic 
_symmetry_space_group_name_H-M    P-1 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, -y, -z' 
 
_cell_length_a                    5.764(5) 
_cell_length_b                    11.669(10) 
_cell_length_c                    21.430(19) 
_cell_angle_alpha                 90.02(2) 
_cell_angle_beta                  95.25(3) 
_cell_angle_gamma                 97.50(5) 
_cell_volume                      1423(2) 
_cell_formula_units_Z             2 
_cell_measurement_temperature     100(2) 
_cell_measurement_reflns_used     4260
_cell_measurement_theta_min       7.27
_cell_measurement_theta_max       68.45
 
_exptl_crystal_description        needle 
_exptl_crystal_colour             red 
_exptl_crystal_size_max           0.16 
_exptl_crystal_size_mid           0.08 
_exptl_crystal_size_min           0.04 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.384 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              620 
_exptl_absorpt_coefficient_mu     3.322 
_exptl_absorpt_correction_type    multi-scan  
_exptl_absorpt_correction_T_min   0.6185 
_exptl_absorpt_correction_T_max   0.8786 
_exptl_absorpt_process_details    'CrystalClear-SM Expert 2.1 b25 (Rigaku, 2013)'  
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       100(2) 
_diffrn_radiation_wavelength      1.54190 
_diffrn_radiation_type            CuK\a 
_diffrn_radiation_source          'Rotating Anode'
_diffrn_radiation_monochromator   'Confocal'
_diffrn_detector                  'PILT'
_diffrn_measurement_device        'AFC11 (Right): Eulerian 3 circle'
_diffrn_measurement_device_type   'Rigaku PILATUS conversion'
_diffrn_measurement_method        'profile data from ω-scans' 
_diffrn_detector_area_resol_mean  5.8140 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             19646 
_diffrn_reflns_av_R_equivalents   0.0590 
_diffrn_reflns_av_sigmaI/netI     0.0457 
_diffrn_reflns_limit_h_min        -5 
_diffrn_reflns_limit_h_max        6 
_diffrn_reflns_limit_k_min        -14 
_diffrn_reflns_limit_k_max        14 
_diffrn_reflns_limit_l_min        -25 
_diffrn_reflns_limit_l_max        25 
_diffrn_reflns_theta_min          7.27 
_diffrn_reflns_theta_max          68.45 
_reflns_number_total              5068 
_reflns_number_gt                 4260 
_reflns_threshold_expression      >2sigma(I) 
 
_computing_data_collection        'CrystalClear-SM Expert 2.1 b25 (Rigaku, 2013)'
_computing_cell_refinement        'CrystalClear-SM Expert 2.1 b25 (Rigaku, 2013)'
_computing_data_reduction         'CrystalClear-SM Expert 2.1 b25 (Rigaku, 2013)'
_computing_structure_solution     'SHELXS (Sheldrick, 2008)' 
_computing_structure_refinement   'SHELXL (Sheldrick, 2008)'
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc  
_refine_ls_weighting_details 
 'calc w=1/[σ²(Fo²)+(0.0941P)²+0.9528P] where P=(Fo²+2Fc²)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          5068 
_refine_ls_number_parameters      376 
_refine_ls_number_restraints      11 
_refine_ls_R_factor_all           0.0706 
_refine_ls_R_factor_gt            0.0640 
_refine_ls_wR_factor_ref          0.1800 
_refine_ls_wR_factor_gt           0.1731 
_refine_ls_goodness_of_fit_ref    1.034 
_refine_ls_restrained_S_all       1.114 
_refine_ls_shift/su_max           0.000 
_refine_ls_shift/su_mean          0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
C1 C -0.0097(5) 0.8245(2) 0.95522(13) 0.0290(6) Uani 1 1 d . . . 
C2 C -0.0835(5) 0.8993(2) 0.90740(13) 0.0301(6) Uani 1 1 d . . . 
H2 H -0.2037 0.9458 0.9132 0.036 Uiso 1 1 calc R . . 
C3 C 0.0215(5) 0.9030(2) 0.85303(13) 0.0297(6) Uani 1 1 d . . . 
C4 C 0.1966(5) 0.8291(2) 0.84459(13) 0.0293(6) Uani 1 1 d . . . 
C5 C 0.2605(5) 0.7599(2) 0.89708(12) 0.0278(6) Uani 1 1 d . . . 
N6 N 0.1572(4) 0.75878(19) 0.95163(10) 0.0283(5) Uani 1 1 d . . . 
C7 C -0.1248(5) 0.8172(2) 1.01524(13) 0.0300(6) Uani 1 1 d . . . 
O8 O -0.0650(4) 0.76119(18) 1.05999(9) 0.0351(5) Uani 1 1 d . . . 
O9 O -0.3017(4) 0.88132(16) 1.01373(9) 0.0326(5) Uani 1 1 d . . . 
C10 C -0.4337(6) 0.8737(3) 1.06818(14) 0.0363(7) Uani 1 1 d . . . 
H10A H -0.5015 0.7933 1.0738 0.054 Uiso 1 1 calc R . . 
H10B H -0.5601 0.9224 1.0623 0.054 Uiso 1 1 calc R . . 
H10C H -0.3289 0.9003 1.1054 0.054 Uiso 1 1 calc R . . 
O11 O -0.0246(4) 0.97343(16) 0.80409(9) 0.0332(5) Uani 1 1 d . . . 
C12 C -0.1885(5) 1.0543(2) 0.81277(13) 0.0329(6) Uani 1 1 d . . . 
H12A H -0.1408 1.0985 0.8523 0.039 Uiso 1 1 calc R . . 
H12B H -0.3475 1.0119 0.8156 0.039 Uiso 1 1 calc R . . 
C13 C -0.1925(6) 1.1363(2) 0.75797(13) 0.0348(6) Uani 1 1 d . . . 
H13 H -0.0291 1.1757 0.7549 0.042 Uiso 1 1 calc R . . 
C14 C -0.2772(6) 1.0729(3) 0.69618(14) 0.0432(8) Uani 1 1 d . . . 
H14A H -0.1729 1.0154 0.6886 0.065 Uiso 1 1 calc R . . 
H14B H -0.2755 1.1285 0.6619 0.065 Uiso 1 1 calc R . . 
H14C H -0.4375 1.0340 0.6983 0.065 Uiso 1 1 calc R . . 
C15 C -0.3481(6) 1.2277(3) 0.77155(15) 0.0438(8) Uani 1 1 d . . . 
H15A H -0.5111 1.1913 0.7719 0.066 Uiso 1 1 calc R . . 
H15B H -0.3389 1.2867 0.7390 0.066 Uiso 1 1 calc R . . 
H15C H -0.2943 1.2639 0.8125 0.066 Uiso 1 1 calc R . . 
C16 C 0.2979(5) 0.8225(2) 0.78841(13) 0.0319(6) Uani 1 1 d . . . 
H16 H 0.2523 0.8677 0.7537 0.038 Uiso 1 1 calc R . . 
C17 C 0.4678(5) 0.7484(2) 0.78373(13) 0.0305(6) Uani 1 1 d . . . 
C18 C 0.5456(5) 0.6820(2) 0.83567(13) 0.0295(6) Uani 1 1 d . . . 
C19 C 0.4394(5) 0.6863(2) 0.89295(13) 0.0291(6) Uani 1 1 d . . . 
C20 C 0.5679(6) 0.7339(2) 0.72606(14) 0.0353(7) Uani 1 1 d . A . 
C21 C 0.7414(6) 0.6645(2) 0.72402(14) 0.0353(7) Uani 1 1 d . . . 
H21 H 0.8141 0.6559 0.6866 0.042 Uiso 1 1 calc R . . 
C22 C 0.8099(5) 0.6058(2) 0.77931(14) 0.0332(6) Uani 1 1 d . . . 
N23 N 0.7180(4) 0.61146(19) 0.83299(11) 0.0305(5) Uani 1 1 d . . . 
O24 O 0.4760(5) 0.79186(18) 0.67748(10) 0.0449(6) Uani 1 1 d . . . 
C25 C 0.544(3) 0.7747(12) 0.6151(6) 0.055(4) Uani 0.761(10) 1 d PD A 1 
H25A H 0.5050 0.6921 0.6030 0.067 Uiso 0.761(10) 1 calc PR A 1 
H25B H 0.7166 0.7953 0.6152 0.067 Uiso 0.761(10) 1 calc PR A 1 
C26 C 0.426(3) 0.8448(11) 0.5692(4) 0.149(8) Uani 0.761(10) 1 d PD A 1 
H26 H 0.4734 0.9290 0.5784 0.179 Uiso 0.761(10) 1 calc PR A 1 
C27 C 0.1670(18) 0.8123(8) 0.5715(3) 0.106(3) Uani 0.761(10) 1 d PD A 1 
H27A H 0.1250 0.7297 0.5619 0.159 Uiso 0.761(10) 1 calc PR A 1 
H27B H 0.0820 0.8573 0.5407 0.159 Uiso 0.761(10) 1 calc PR A 1 
H27C H 0.1244 0.8286 0.6136 0.159 Uiso 0.761(10) 1 calc PR A 1 
C28 C 0.469(3) 0.8149(11) 0.5023(4) 0.184(8) Uani 0.761(10) 1 d PD A 1 
H28A H 0.4332 0.7312 0.4954 0.276 Uiso 0.761(10) 1 calc PR A 1 
H28B H 0.6341 0.8397 0.4957 0.276 Uiso 0.761(10) 1 calc PR A 1 
H28C H 0.3677 0.8546 0.4727 0.276 Uiso 0.761(10) 1 calc PR A 1 
C25' C 0.571(8) 0.778(4) 0.622(2) 0.046(9) Uiso 0.239(10) 1 d PD A 2 
H25C H 0.5516 0.6955 0.6096 0.055 Uiso 0.239(10) 1 calc PR A 2 
H25D H 0.7402 0.8082 0.6258 0.055 Uiso 0.239(10) 1 calc PR A 2 
C26' C 0.438(3) 0.8455(17) 0.5749(10) 0.046(5) Uiso 0.239(10) 1 d PD A 2 
H26' H 0.3127 0.7791 0.5643 0.055 Uiso 0.239(10) 1 calc PR A 2 
C27' C 0.265(2) 0.9314(10) 0.5772(5) 0.034(4) Uiso 0.239(10) 1 d PD A 2 
H27D H 0.2818 0.9846 0.5420 0.051 Uiso 0.239(10) 1 calc PR A 2 
H27E H 0.2966 0.9752 0.6167 0.051 Uiso 0.239(10) 1 calc PR A 2 
H27F H 0.1053 0.8902 0.5742 0.051 Uiso 0.239(10) 1 calc PR A 2 
C28' C 0.538(3) 0.8410(18) 0.5114(9) 0.044(4) Uiso 0.239(10) 1 d PD A 2 
H28D H 0.5005 0.9080 0.4867 0.066 Uiso 0.239(10) 1 calc PR A 2 
H28E H 0.4674 0.7698 0.4890 0.066 Uiso 0.239(10) 1 calc PR A 2 
H28F H 0.7084 0.8423 0.5177 0.066 Uiso 0.239(10) 1 calc PR A 2 
C29 C 1.0003(5) 0.5305(2) 0.77482(14) 0.0353(7) Uani 1 1 d . . . 
O30 O 1.0926(4) 0.5203(2) 0.72703(10) 0.0448(6) Uani 1 1 d . . . 
O31 O 1.0559(4) 0.47806(17) 0.82800(10) 0.0378(5) Uani 1 1 d . . . 
C32 C 1.2385(6) 0.4034(3) 0.82597(17) 0.0420(7) Uani 1 1 d . . . 
H32A H 1.1807 0.3369 0.7983 0.063 Uiso 1 1 calc R . . 
H32B H 1.2802 0.3762 0.8683 0.063 Uiso 1 1 calc R . . 
H32C H 1.3776 0.4467 0.8100 0.063 Uiso 1 1 calc R . . 
N33 N 0.5036(4) 0.6242(2) 0.94306(11) 0.0332(5) Uani 1 1 d . . . 
H33A H 0.6141 0.5793 0.9410 0.058(12) Uiso 1 1 calc R . . 
H33B H 0.4351 0.6285 0.9779 0.035(8) Uiso 1 1 calc R . . 
C50 C 0.6737(6) 0.5923(3) 0.37914(15) 0.0443(8) Uani 1 1 d . . . 
H50 H 0.7088 0.5435 0.3437 0.053 Uiso 1 1 calc R . . 
Cl1 Cl 0.36727(15) 0.58532(7) 0.37933(4) 0.0500(3) Uani 1 1 d . . . 
Cl2 Cl 0.80334(16) 0.73505(9) 0.36896(5) 0.0589(3) Uani 1 1 d . . . 
Cl3 Cl 0.79082(18) 0.53719(10) 0.45031(5) 0.0677(3) Uani 1 1 d . . . 
O60 O 0.2436(4) 0.5833(2) 0.06574(11) 0.0438(6) Uani 1 1 d D . . 
H60A H 0.146(6) 0.630(3) 0.0475(16) 0.056(11) Uiso 1 1 d D . . 
H60B H 0.186(7) 0.548(3) 0.0984(14) 0.063(12) Uiso 1 1 d D . . 
 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
C1 N6 1.313(4) . ? 
C1 C2 1.418(4) . ? 
C1 C7 1.498(4) . ? 
C2 C3 1.359(4) . ? 
C3 O11 1.361(3) . ? 
C3 C4 1.433(4) . ? 
C4 C16 1.392(4) . ? 
C4 C5 1.434(4) . ? 
C5 N6 1.359(4) . ? 
C5 C19 1.434(4) . ? 
C7 O8 1.210(4) . ? 
C7 O9 1.339(4) . ? 
O9 C10 1.447(4) . ? 
O11 C12 1.442(4) . ? 
C12 C13 1.516(4) . ? 
C13 C15 1.524(5) . ? 
C13 C14 1.525(4) . ? 
C16 C17 1.398(4) . ? 
C17 C18 1.428(4) . ? 
C17 C20 1.430(4) . ? 
C18 N23 1.376(4) . ? 
C18 C19 1.424(4) . ? 
C19 N33 1.347(4) . ? 
C20 O24 1.347(4) . ? 
C20 C21 1.370(5) . ? 
C21 C22 1.419(4) . ? 
C22 N23 1.315(4) . ? 
C22 C29 1.502(5) . ? 
O24 C25' 1.37(6) . ? 
O24 C25 1.449(15) . ? 
C25 C26 1.457(11) . ? 
C26 C27 1.499(14) . ? 
C26 C28 1.525(9) . ? 
C25' C26' 1.49(2) . ? 
C26' C27' 1.507(18) . ? 
C26' C28' 1.527(18) . ? 
C29 O30 1.209(4) . ? 
C29 O31 1.327(4) . ? 
O31 C32 1.455(4) . ? 
C50 Cl2 1.756(4) . ? 
C50 Cl1 1.758(4) . ? 
C50 Cl3 1.767(4) . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
N6 C1 C2 124.9(3) . . ? 
N6 C1 C7 115.5(2) . . ? 
C2 C1 C7 119.7(3) . . ? 
C3 C2 C1 118.5(3) . . ? 
C2 C3 O11 125.1(3) . . ? 
C2 C3 C4 119.7(3) . . ? 
O11 C3 C4 115.3(2) . . ? 
C16 C4 C3 122.4(3) . . ? 
C16 C4 C5 121.1(3) . . ? 
C3 C4 C5 116.4(3) . . ? 
N6 C5 C4 123.2(3) . . ? 
N6 C5 C19 117.0(2) . . ? 
C4 C5 C19 119.8(3) . . ? 
C1 N6 C5 117.3(2) . . ? 
O8 C7 O9 123.8(3) . . ? 
O8 C7 C1 124.4(3) . . ? 
O9 C7 C1 111.7(2) . . ? 
C7 O9 C10 115.7(2) . . ? 
C3 O11 C12 116.6(2) . . ? 
O11 C12 C13 109.4(2) . . ? 
C12 C13 C15 108.2(3) . . ? 
C12 C13 C14 111.8(2) . . ? 
C15 C13 C14 111.5(3) . . ? 
C4 C16 C17 119.2(3) . . ? 
C16 C17 C18 121.8(3) . . ? 
C16 C17 C20 121.3(3) . . ? 
C18 C17 C20 116.9(3) . . ? 
N23 C18 C19 117.5(3) . . ? 
N23 C18 C17 123.0(3) . . ? 
C19 C18 C17 119.5(3) . . ? 
N33 C19 C18 121.9(3) . . ? 
N33 C19 C5 119.5(3) . . ? 
C18 C19 C5 118.6(3) . . ? 
O24 C20 C21 125.9(3) . . ? 
O24 C20 C17 114.5(3) . . ? 
C21 C20 C17 119.6(3) . . ? 
C20 C21 C22 118.3(3) . . ? 
N23 C22 C21 125.1(3) . . ? 
N23 C22 C29 118.4(3) . . ? 
C21 C22 C29 116.4(3) . . ? 
C22 N23 C18 116.9(3) . . ? 
C20 O24 C25' 114.8(14) . . ? 
C20 O24 C25 119.9(5) . . ? 
C25' O24 C25 8(2) . . ? 
O24 C25 C26 111.6(11) . . ? 
C25 C26 C27 107.3(12) . . ? 
C25 C26 C28 112.1(10) . . ? 
C27 C26 C28 104.2(11) . . ? 
O24 C25' C26' 106(3) . . ? 
C25' C26' C27' 136(3) . . ? 
C25' C26' C28' 110(3) . . ? 
C27' C26' C28' 112.9(15) . . ? 
O30 C29 O31 124.2(3) . . ? 
O30 C29 C22 122.4(3) . . ? 
O31 C29 C22 113.4(3) . . ? 
C29 O31 C32 115.6(2) . . ? 
Cl2 C50 Cl1 110.9(2) . . ? 
Cl2 C50 Cl3 110.28(19) . . ? 
Cl1 C50 Cl3 109.33(19) . . ? 
 
loop_ 
 _geom_torsion_atom_site_label_1 
 _geom_torsion_atom_site_label_2 
 _geom_torsion_atom_site_label_3 
 _geom_torsion_atom_site_label_4 
 _geom_torsion 
 _geom_torsion_site_symmetry_1 
 _geom_torsion_site_symmetry_2 
 _geom_torsion_site_symmetry_3 
 _geom_torsion_site_symmetry_4 
 _geom_torsion_publ_flag 
N6 C1 C2 C3 1.2(4) . . . . ? 
C7 C1 C2 C3 -179.1(2) . . . . ? 
C1 C2 C3 O11 -177.5(2) . . . . ? 
C1 C2 C3 C4 2.1(4) . . . . ? 
C2 C3 C4 C16 175.1(2) . . . . ? 
O11 C3 C4 C16 -5.3(4) . . . . ? 
C2 C3 C4 C5 -3.9(4) . . . . ? 
O11 C3 C4 C5 175.8(2) . . . . ? 
C16 C4 C5 N6 -176.3(2) . . . . ? 
C3 C4 C5 N6 2.7(4) . . . . ? 
C16 C4 C5 C19 2.9(4) . . . . ? 
C3 C4 C5 C19 -178.2(2) . . . . ? 
C2 C1 N6 C5 -2.4(4) . . . . ? 
C7 C1 N6 C5 177.8(2) . . . . ? 
C4 C5 N6 C1 0.4(4) . . . . ? 
C19 C5 N6 C1 -178.8(2) . . . . ? 
N6 C1 C7 O8 4.2(4) . . . . ? 
C2 C1 C7 O8 -175.5(3) . . . . ? 
N6 C1 C7 O9 -176.3(2) . . . . ? 
C2 C1 C7 O9 3.9(3) . . . . ? 
O8 C7 O9 C10 -4.5(4) . . . . ? 
C1 C7 O9 C10 176.1(2) . . . . ? 
C2 C3 O11 C12 3.6(4) . . . . ? 
C4 C3 O11 C12 -176.0(2) . . . . ? 
C3 O11 C12 C13 172.0(2) . . . . ? 
O11 C12 C13 C15 -174.5(2) . . . . ? 
O11 C12 C13 C14 62.4(3) . . . . ? 
C3 C4 C16 C17 180.0(2) . . . . ? 
C5 C4 C16 C17 -1.1(4) . . . . ? 
C4 C16 C17 C18 -2.0(4) . . . . ? 
C4 C16 C17 C20 176.6(2) . . . . ? 
C16 C17 C18 N23 -177.7(2) . . . . ? 
C20 C17 C18 N23 3.6(4) . . . . ? 
C16 C17 C18 C19 3.3(4) . . . . ? 
C20 C17 C18 C19 -175.3(2) . . . . ? 
N23 C18 C19 N33 0.0(4) . . . . ? 
C17 C18 C19 N33 179.0(2) . . . . ? 
N23 C18 C19 C5 179.5(2) . . . . ? 
C17 C18 C19 C5 -1.5(4) . . . . ? 
N6 C5 C19 N33 -2.8(4) . . . . ? 
C4 C5 C19 N33 178.0(2) . . . . ? 
N6 C5 C19 C18 177.7(2) . . . . ? 
C4 C5 C19 C18 -1.5(4) . . . . ? 
C16 C17 C20 O24 -3.3(4) . . . . ? 
C18 C17 C20 O24 175.3(2) . . . . ? 
C16 C17 C20 C21 177.1(3) . . . . ? 
C18 C17 C20 C21 -4.2(4) . . . . ? 
O24 C20 C21 C22 -177.2(3) . . . . ? 
C17 C20 C21 C22 2.3(4) . . . . ? 
C20 C21 C22 N23 0.7(4) . . . . ? 
C20 C21 C22 C29 179.9(2) . . . . ? 
C21 C22 N23 C18 -1.4(4) . . . . ? 
C29 C22 N23 C18 179.4(2) . . . . ? 
C19 C18 N23 C22 178.1(2) . . . . ? 
C17 C18 N23 C22 -0.8(4) . . . . ? 
C21 C20 O24 C25' 0(2) . . . . ? 
C17 C20 O24 C25' -180(2) . . . . ? 
C21 C20 O24 C25 6.0(9) . . . . ? 
C17 C20 O24 C25 -173.5(8) . . . . ? 
C20 O24 C25 C26 180.0(10) . . . . ? 
C25' O24 C25 C26 -130(19) . . . . ? 
O24 C25 C26 C27 -57.9(14) . . . . ? 
O24 C25 C26 C28 -171.8(12) . . . . ? 
C20 O24 C25' C26' 178.0(18) . . . . ? 
C25 O24 C25' C26' 45(16) . . . . ? 
O24 C25' C26' C27' 10(5) . . . . ? 
O24 C25' C26' C28' 177(2) . . . . ? 
N23 C22 C29 O30 179.6(3) . . . . ? 
C21 C22 C29 O30 0.4(4) . . . . ? 
N23 C22 C29 O31 -0.7(4) . . . . ? 
C21 C22 C29 O31 -179.9(2) . . . . ? 
O30 C29 O31 C32 -0.8(4) . . . . ? 
C22 C29 O31 C32 179.6(2) . . . . ? 
 
_diffrn_measured_fraction_theta_max    0.971 
_diffrn_reflns_theta_full              68.45 
_diffrn_measured_fraction_theta_full   0.971 
_refine_diff_density_max    0.800 
_refine_diff_density_min   -0.634 
_refine_diff_density_rms    0.075 
